Modern chemical synthesis techniques have allowed for improved incorporation of nano‐scale additives into solid propellants. Various. Kumar Ishitha, P. A. Ramakrishna. () Activated charcoal: as burn rate modifier and its mechanism of action in non-metalized composite solid propellants. The combustion of hydroxyl-terminated polybutadiene (HTPB) propellants containing ne ammonium perchlo- rate (AP) was investigated using laser-excited, .

Author: Shakajar Kazigul
Country: Ukraine
Language: English (Spanish)
Genre: Technology
Published (Last): 21 September 2010
Pages: 281
PDF File Size: 5.37 Mb
ePub File Size: 12.79 Mb
ISBN: 689-7-50689-696-4
Downloads: 2365
Price: Free* [*Free Regsitration Required]
Uploader: Gomi

Ammonium perchlorate composite propellant

The phenomenon can be explained by considering the heat-flux-to-mass ratio: Catalysts always play a key role in heat releasing procedure of propellant. The burn pfopellants such as linear burn rate are often determined prior to rocket motor firing using a strand burner test.

A heating rate of 0. Help us write another book on this subject and reach those readers. The combustion simulation results may be observed in the figure below, which show the behavior of AP combustion with different internal pressures of the combustion chamber. This article includes a list of referencesbut its sources remain unclear because it has insufficient inline citations. Views Read Edit View history. For practical purposes the Arrhenius parameters, like the corrected reaction order, can be used to estimate the overall rate constant k for thermal decomposition using the eq.

This correlation can be used to determine the burning rate characteristics of a composite solid propellant with a specific formulation. When a composite propellant is used, like AP-HTPB, the combustion process depends on the diffusion of the gases aap on the initial decomposition of the oxidizer, which surrounds the binder molecules at the burning surface.

Less RSD value is the stand of less change, or less instability, of the explosion heat releasing of the propellant sample. Due proplelants, the flame structure of AP composite propellants is complex and locally three-dimensional in shape.

During the combustion, at the burning surface, the decomposed gases from the ammonium perchlorate particles and fuel binder HTPB are interdiffused and produce diffusion flame streams.


Ammonium perchlorate composite propellant – Wikipedia

However, the excellent catalysis of nanocatalyst still htph many researchers to study [ 4 — 6 ]. By using this site, you agree to the Terms of Use and Privacy Policy. Other methods should be employed to improve the dispersibility of nanocatalyst in the propellant.

Subscribe to Table of Contents Alerts. The addition of burning rates catalysts like Fe 2 O 3 on the propellant formulation alters the thermal decomposition behavior of AP, and consequently the thermal decomposition behavior of the propellant. This behavior should be attributed to the homogeneous dispersion of AP admist the binder, in the solid phase, and to the lack of this species in relation to the binder generating lower concentrations of O 2 than necessary.

The xp mechanism of AP has been studied and modified. Both agencies set forth rules regarding the impulse classification of rocket motors and the level of certification required by rocketeers in order to purchase certain impulse size motors. Three representative areas of each sample were chosen to test its decomposition temperature by DSC.

Retrieved from ” https: The Ozawa method is one of the most popular methods for estimating activation energies by linear heating rate and it is the so-called isoconversional method.

There was a problem providing the content you requested

During the combustion process ;ropellants AP crystals at high pressures, is possible to observe the formation of a tiny layer of ammonium perchlorate in liquid propellangs at the grain surface [ 3 ], followed by a region where it is presented in gaseous phase.

Every combustion heat data of the three areas is a mean value of three testing data. Based on combustion mechanisms, the burning process may be simulated and analyzed by some specific softwares.

Cite this chapter Copy to clipboard R. The table below shows the elementary reactions which take part on the combustion process. How to cite and reference Link to this ntpb Copy to clipboard. Therefore, the dispersibility of propelpants is very important to the heat releasing of propellants. Meanwhile, the decrease ratios of STD and RSD of the explosion heat are very smooth when kneading time of propellant less than 3 hours. The composition of APCP can vary significantly depending on the application, intended burn characteristics, and constraints such as nozzle thermal limitations or specific impulse Isp.


The synthetic aging process was conducted by exposing the cured propellant formulation to a temperature of K for days pfopellants a muffle FNT-F3-T W that was monitored day by day during this period. Kissinger [ 15 ] and Ozawa [ 16 ] and Flynn [ 17 ] demonstrated that differential scanning calorimetry DSC technique, based on the linear relation between peak temperature and heating rate, can be used to determine the kinetics parameters of a thermal decomposition activation energy, rate constant.

This mechanism was proposed by Gross [ 6 ], according to literature data. In small APCP motors with high aluminum content, the residence time of the combustion gases does not allow for full combustion of the aluminum and thus a substantial fraction of the aluminum is burned outside the combustion chamber, leading to decreased performance. They were both derived from the basic kinetic equations for heterogeneous chemical reactions and therefore have a wide application, as it is not necessary to know the reaction order [ 19 ] or the conversional function to determine the kinetic parameters.

January 23rd DOI: Proellants exothermic events have different maximum temperatures in both cases; the higher the heating rate, higher is the maximum temperature of the peak. It is obtained by reaction between ammonia and perchloric acid, or by double decomposition between an ammonium salt and sodium perchlorate, and crystallizes with romboedric structure in room temperature and pressure, with relative density of 1.